Source: http://news.feedzilla.com/en_us/stories/politics/top-stories/209771294?client_source=feed&format=rss
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Samsung tweaking Face Unlock to require blinking, smiling still optional originally appeared on Engadget on Thu, 29 Mar 2012 12:41:00 EDT. Please see our terms for use of feeds.
PermalinkSource: http://www.engadget.com/2012/03/29/samsung-face-unlock-blinking-feature/
Rapper opens up about Angola incident for the first time on today's 'RapFix Live' at 4 p.m. ET on MTV.com.
By Rob Markman, with reporting by Sway Calloway
Nas on "RapFix Live"
Photo: MTV News
Musically, Nas has given so much of himself during the course of his 18-year rap career. But in the media, the Queensbridge MC is usually reserved and soft-spoken. Still, it was hard for God's Son to hold back when he was accused of skipping out on a New Year's show in Africa, which led an American concert promoter and his son to be kidnapped.
On today's (March 28) "RapFix Live," Nas finally gives his side of the story. "I didn't want to touch on it because it seemed like he was in grave danger out there," Nas said Tuesday during the interview, which will stream on MTV.com today at 4 p.m. ET.
The promoter returned home safely to New Jersey on February 19. TMZ broke the story January 3 and reported that Patrick Allocco and his son, whom he works with, were kidnapped by local Africa promoter Henrique "Riquhino" Miguel after Nas and an opening act failed to perform at a New Year's Eve concert in Angola.
Allocco's reps told TMZ that Nas and opening act Jemiah Jai were paid to perform two shows but failed to board their flights. Once Miguel realized that Nas wasn't going to perform, he sent his people to take Allocco and his son into custody at gunpoint. Nas eventually returned the $300,000 that was paid to him, and Allocco was released and allowed to return back to the U.S.
Now, Esco is ready to open up.
"Basically he was a promoter that I never worked with, and he wanted me to come to Africa for New Year's, which, for me, I thought, would be the best way to spend New Year's. ... The business wasn't handled. There was nothing sent to me, and there were no flights," he said. "By the time he did send money — he did eventually send money to me — but it was too late to go. I didn't even have a visa to get in the country. So that's canceled, the show's canceled."
Allocco, who is now contemplating litigation, has a differing account, contending that everything was in place for Nas to travel to Africa. "Nothing could be further from the truth," Allocco told MTV News of Nas' version of the story. "Nas put us in harm's way by not showing up and put my son and I at physical harm and at risk by his inaction to fly to Angola."
"That was just all wrong. Anytime I'm supposed to go to Africa, it happens," Nas said on "RapFix Live." "When people take care of business, it happens. ... You booked the flight but no return flight. I didn't have a visa, and you didn't send money till after I was supposed to jump on the plane to another country, and that's just the way it went down."
Catch Nas, Killer Mike, Bun B and Prodigy on a special episode of "RapFix Live" today at 4 p.m. ET on MTV.com, when all four esteemed lyricists will address the tragic shooting death of Florida teen Trayvon Martin and more. Send your comments and thoughts on the unfortunate situation via Twitter using the hashtag #RapFixLive.
Related ArtistsSource: http://www.mtv.com/news/articles/1681956/nas-concert-promoter-kidnapped.jhtml
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Article by clarisse bwown
Home improvements have been shown to significantly increase the value of property, make homes a safer place for children and improve the quality of life for everyone in the home. Contacting a professional is a vital first step for you to make your home happen, really learn more about Home Improvement services and make yourself at home.
Improvement
Prices for most remodeling projects continue to climb, while the recoup value of improvements at resale is declining to levels last seen in 2002. A number of improvements designed to make the report more reliable and useful has also affected both cost and value data. Similarly, home improvement projects often paid for themselves through a comparable increase in the home?s value. A local authority can offer different types of help with home improvements. To find out if you can get help with home improvements and the help available in your area, contact your local authority. Your rights when you apply for help with home improvements.
Although your local authority can have its own rules, there are certain things that it must or must not do when it provides help with home improvements. Your local authority must have rules about help with home improvements, but it cannot have rules which are completely rigid or unreasonable. When you apply for help with home improvements your local authority must:-make sure that a copy of its rules, including the types of help it provides, are available for you to look at, free of charge, at its main office.
If you would like help with applying for home improvements, you can consult an experienced adviser, for example, at a Citizens Advice Bureau. If you rent your home and apply to your local authority for help with home improvements, you will need to get your landlord?s permission before the local authority will agree to help you.
Kitchen
Kitchen renovations or upgrades are among the best ways to increase the value of your house. There are many levels of home improvement from the simple aspects of new curtains and blinds, carpets and flooring and furniture to the more involving, such as building work, conservatories, fitted kitchens and double glazing. Some insist that kitchen renovations give you the best bang for your buck. But, it?s important to remember that fads and trends for kitchens and other rooms come and go quickly. If you do a kitchen renovation, for example, you?ll recoup 92 percent of your money. A no frills kitchen remodel will get you an 80 percent return. Upgrading the countertop, adding a backsplash, replacing dated hardware and changing the color of the walls can go along way to adding new life to a tired kitchen.
A lot of people get involved in do it yourself home improvements without really considering what is needed beforehand. That means that you need to clearly define what the purpose of your project really is before you even get started.
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Home Improvement Is Just Easy! energy efficient rebate is unique because it is actually a effective phenomenon impinging on millions of people. Perhaps you have noticed this at some time or another throughout the course of the day. When you start reading more, you will recognize all that is included and it might surprise you. But many persons have a decent perspective about most different results. Not only that, but it is actually entirely all-natural and normal with like to find what you may be searching for. We hope with broaden your knowledge base of the specific subject, and in so doing make it possible for you with be more informed.
Planning house improvement augmentation can be thrilling with do, yet it?s important with turn over in ones mind every element at the onset. People shouldn?t feel an urgency about leaping into action and getting building materials or contractors earlier than understanding what you may be going to do. You need to be sure you stay in your budget, for example, and that you?re considering factors like stamina efficiency and durability and how factors look.
Few factors have a greater impact found on the look of the house than the light. A huge difference can be had with switching lamps and bulbs, and these are usually changes that aren?t too expensive or difficult. As an example, a gorgeous chandelier in the front space might bring a classy look with the entire space. Another choice that has a more streamlined look compared with traditional fixtures is the recessed light, that is not difficult with place in, so you would like to take this into consideration for a limited rooms in your dwelling. Another thing with consider regarding lights are the windows, in certain instances the addition of the hot window or turning them into a greater 1 might seriously create a space brighter. To create the nearly all of a rooms light, the types of lights you have and how they are placed is anything you should program strategically too. You possibly are aware of the range that senior center covers, and that proved with create it difficult with decide on what we sought with cover.
Having so much to select from really can create factors more interesting when you may be researching information.
What you are able to and could do is look for your self because we learn there are different ideal sources online.
Everything you are able to find out is of service with you in some technique, and perhaps that is in the far off future; but that is all proper. Anybody can analysis anything and read it, but it is actually how you assimilate that knowledge that makes a huge difference. New windows aren?t automatically a need, should you don?t like to modify the technique your windows look, or the complete space. Individuals can create ideal changes with the addition of present drapes, curtains or blinds. People may have no realization of the payoff this may have on their abode, since this impacts the light, color and the room?s insulation even. Blinds that are quality prevent glare while allowing greater light, which depends on your preference. Obtaining the correct color and fashion mixture of curtain can completely change the appearance of the house. For this reason, look carefully at what covers your windows with figure out if a change would be a wise thing.
Consider adding plants and different greenery with your house, both inside and out. Hedges, shrubbery, or any sort of greenery added with the outside of the house can create it look fairly livable and gorgeous.
A garden is a ideal thing to add too. Having a garden can be beneficial in a range ways outside of easy aesthetic appeal. The yard of the house can be livened up with a garden, particularly should you plant vegetables or flowers. Houseplants are moreover fairly practical, particularly inside of the house. The decor and ambiance of the space can moreover benefit if the plant is big.
There are many ways with accomplish house improvement projects, a limited of which were stated in this short article. Imagine several different improvements that you want to create on your house before you really implement the projects. Remember with never hire anyone without finding out much more about what they really can do, and never buy anything without researching the material first.
We know you want to find out much more about career training online, and coming up upcoming is anything we believe may assist you in ways you do not realize, yet. The range of that you can buy information is staggering, and what I have found is many persons merely receive lost. We may explain in more detail why persons should be careful when they read about this.
Source: http://camisecretreviews.org/easy-and-cost-effective-home-improvement-plans
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Home Staging is the art of rearranging and dressing a home to make it more appealing to prospective buyers. The whole purpose of home staging is to achieve a neutral but inviting look that will highlight all the selling points of a house and make the potential clients forget about the less desirable details, thus covering a wide range of tastes and therefore buyers.
And then again you might not want to sell your house and just want to scare potential clients away, in which case home staging also helps if it?s turned into a horror show, and here is the way to do it:
Do no gardening for at least three or four weeks. You want buyers to be overcome with horror, not the joy of a well-kept, fairy-tale garden.
Don?t you dare mend anything that?s broken around the house ? broken windows and doors falling off their hinges always give a house a horror movie look.
Cleaning should be a thing of history ? best forgotten. Your visitors should have dust in their lungs to fill up a mile-long road when they leave, and enough cobwebs in their hair to make a nice cap. If they still make it to the kitchen, make sure you show them your dirty dishes collection ? they?re going to love that.
Keep every room as dull and dreary as possible. Leave lights and lamps off, close the drapes and leave the trees to block out the sun. This way the sale of your home will be as good as dead.
It would be a great idea if your visitors couldn?t walk through the house without stepping on a cat?s tail or stumbling on a sleeping dog, so ask your neighbors to do the neighborly thing and lend their pets to you for the day.
Do not clean the bathroom, no one is going to use it are they? Leave the ring round the bath and the mildew in the shower ? at least it adds some color!
Close all the windows the week before show day, and spend the week cooking pungent foods and smoking cigars. Oxygen masks are back in fashion.
Bug is the word of the day. People just go crazy for a bug-infested house, so don?t waste any time in filling it. Organize an open-doors day for the pesky little creatures and lure them in with refreshments.
There are two sides to hell and you need to show your clients both. If it?s cold outside turn off the heat and soon your house will be as cold as a grave or the North Pole. If on the other hand it?s hot outside, turn the heat on and let the visitors melt away.
Suffocate your visitors with your lovely presence. You need to keep a close watch on your visitors every second of their tour and while you keep them from nosing into your cupboards and cabinets, entertain them with an endless account of your spiteful neighbors and the beasts they keep as pets.
If you do all of this, the chances are pretty good that you will never sell your house. Much of the home staging is all about having a good judgment. A home that is clean and tidy, that doesn?t smell like yesterday?s trash will attract a lot more clients, so if selling your home is your wish, try to disregard all of the above.
We?re your guide to best ab workout.
Source: http://realnews.galanter.net/2012/03/28/home-staging-a-horror-show-for-the-unsuspecting-buyer/
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How Work at Home Moms Can Get the Work Done
As if being a fulltime ma is not nerve-wrangling enough, add to this the fact that work at home moms still have jobs to fulfill all in a day?s work. The challenge is finding the time and the will to do all of these things without losing the insanity of the full time mom.
If you have to or want to work from home in Montreal, select at home part-time work that give you flexibility in schedule. Then, to get things done, work round the schedule of your kids. Your children are your first concern so you must grab each chance you get to be with them, play with them and attend to their needs.
Do work from your home during the down time of your youngsters. There are lots of Montreal work at home opportunities available that base the income not on the hours you input but on every task finished. This way, you aren't bounded by time but you may be as flexible about it as you want to.
Additionally , doing work from home Montreal is exhausting so don't wait to enlist some help if necessary. If your kids are the right age, you can ask them to set the table and store away their toys. Having work from home in Canada means you can't do all jobs at home so have your husband share with the chores. Part-time home work in Montreal will let you and your better half work together better to keep the house running.
As for the final information, let your things in your home be at it is even for a bit. If you have work at home to take care of, let your washing pile up even for just 1 or 2 days. Let dust gather a bit. These are excusable given your current situation.
For more information on openings to be had for work at home in Montreal please visit Claude Fullinfaw?s blog on topics about work from your home.
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Home improvement has always been a popular interest of people. Many people add onto their house or upgrade it, while many people want to fix it up for cosmetic reasons. There is always something that needs to be done when you own a house. This article can help you to find out which improvements are the easiest and can net you the most return for your money.
Are you tired of looking at the worn down bushes in front of your house? Why not give them a new breath of life by trimming them down and shaping them. When you take the time to trim your bushes and shape them, they look much cleaner and add a nice touch to your home.
Replacing an entire floor with wood, carpet, or tile can be a very costly project. One affordable and easy option is to pull up existing flooring, then apply a colored stain to the bare concrete. This creates a modern, industrial-inspired look that is highly versatile and easily changed to accommodate different decor.
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If you heat with a wood stove, smoke will cause your walls to become dingy and you will need to repaint more often than if you heat with a furnace. When you do repaint, it is worthwhile to wipe the walls and ceiling down with a damp sponge to remove as much soot as possible before putting on a new coat of paint.
Fun fact, most dishwashers, when full, are actually more efficient than washing dishes by hand. The water consumed is likely less than the amount you use to wash your own dishes. Bonus, it is faster, and typically the washer will dry your dishes too. If you are looking into buying a new appliance for your home, consider a dishwasher.
If you really want to change the value of your home, you will have to become involved in some kind of home improvement. If you don?t have a lot of money, you should think about investing only in a simple decorator, in order to help you make the key decisions in what you should change.
Get multiple quotes from contractors before choosing one for your home improvements. Research their references and physically go to see the work done for yourself. Any contractor who doesn?t offer you a list of references is not trustworthy and you should avoid them like the plague! Remember, you get what you pay for.
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As you begin your home improvement project, take care not to demolish too quickly. You should always check the structure behind a wall or a cabinet before you tear it down. If there are electrical components involved, you may have to spend a lot of money to fix the mess that you made.
Store your building material in between your ceiling rafters or floor joists. Long pieces of molding and even larger materials like two by fours can be stored up and out of the way just with a little effort on your part. Simply nail a couple of furring strips across two of your exposed floor joists or rafters and slip in the material to be stored.
A great way to add a new look to any room of the home is to tile or re-tile the floors. Tile flooring comes in thousands of colors and designs and is relatively inexpensive when you do it yourself. For as little as $1 a square foot, new tile floors can be an excellent home improvement project.
If one is looking for a way to improve their home as well as provide themselves with a supply of fresh food then building a small chicken coop may be the thing to do. Not only will it provide one with a supply of eggs but it can even bring in money if one sells the eggs.
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If you sit on your chair cushions long enough, eventually they flatten. A great way to bring life back to your cushions is setting them in the sun. The sun helps the moisture evaporate from the cushion?s fillings, bringing the bounce back. Make sure to flip the sides of the cushion, and don?t leave it out too long, as the sun can make the fabric colors fade.
Before you begin your next home improvement project, ask for help from friends and family members. If you wait until you have already started, it may be difficult to find the help you need. You may also have trouble finishing your project on time, adding extra stress to your work.
Childproofing your home can have a lot of great long- term effects. Your child will grow up much healthier if you make sure that your home is safe from harmful gases and contaminating microscopic particles. Such steps to keep your child safe should begin with conception and not after your baby is born.
When working with power tools, always read the instruction manuals in regards to the specific tool you are working with. If you do not know how or have very little experience working with a tool, read and understand how it works before plugging it in. Power tools are very dangerous so understand them before operation.
If you don?t have time to take care of your lawn, or don?t want to pay to have it professionally maintained, consider putting in a low maintenance yard. This usually consists of rock beds with hearty plants that need little water. This option will cut down on maintenance time and water costs.
If you find that your utility bills are through the roof, consider having someone come and inspect your home for efficiency issues. Often you will find that your windows and doors need to be replaced, and the new ones will pay for themselves in no time with the savings on your heating bill.
With careful reasearch and planning, most people can do some home improvement with good results. It?s not always as easy as it looks though, and one should proceed with caution. It?s easy to get into a project and find it is much more costly and complicated than it looked in the beginning.
Source: http://www.scd2011.com/solve-problems-for-the-get-it-done-yourselfer-with-these-quick-tips/
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[ [ [['Afghan security forces and police killed three', 3]], 'http://yhoo.it/H9BcJE', '[Related: Bales\' wife on his alleged shooting: \'He would not do that\']', ' ', '630', ' ', ' ', ], [ [['looking for fireworks between the opposing camps', 16]], 'http://yhoo.it/GSvEsj', '[RELATED:\?It?s going to be a circus\?: Activists begin protests outside Supreme Court]', ' ', '630', ' ', ' ', ], [ [['entirely respectable way to put off the searing constitutional controversy', 8]], 'http://yhoo.it/GE6jSh', '[RELATED: Obama\?s health care law passed 2 years ago, but where are we now\?]', ' ', '630', ' ', ' ', ], [ [['Witnesses said the gunman pulled up on a black scooter', 7]], 'http://yhoo.it/GzwOIW', '[Related: New York police tighten security at Jewish sites]', ' ', '630', ' ', ' ', ], [ [['test Zimmerman for alcohol or drugs', 11]], 'http://yhoo.it/Gzn6VF', '[Related: White House says Trayvon Martin is local issue]', ' ', '630', ' ', ' ', ], [ [['Trayvon Martin decked the Neighborhood', 7]], 'http://yhoo.it/GUovUP', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/2/61/261d2c36bccf0971c2734a4d4398aa5a.jpeg', '512', ' ', 'AP/David Goldman', ], [ [['entirely respectable way to put off the searing constitutional controversy', 12]], 'http://news.yahoo.com/photos/tea-party-activists-defy-rain-to-rip-obama-health-care-law-slideshow/', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/4/31/431f2f4f7ed388d5bc5557b0a76267fa.jpeg', '450', ' ', 'Reuters/Jonathan Ernst', ], [ [['associated with such a small earthquake', 4]], 'http://yhoo.it/GTco9z', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/0/b4/0b493c1a47b6e3f97f8f48a2b251d7d4.jpeg', '630', ' ', 'AP Photo/Carrie Antlfinger', ], [ [['Fox News host Geraldo Rivera sparked outrage', 3]], 'http://yhoo.it/GKMVTk', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/2/7c/27c7367bc512d233ae1790b320a5e92c.jpeg', '630', ' ', 'AP Photo/John Minchillo', ], [ [['The charges signed against Bales include', 1]], 'http://yhoo.it/wZT5zV', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/7/a0/7a07c51b2aa0f39b1a23355046d13870.jpeg', '512', ' ', 'AP Photo/DVIDS\, Spc\. Ryan Hallock\, File', ], [ [['George Zimmerman, if I had a son', 6]], 'http://news.yahoo.com/photos/thousands-protest-fla-teen-death-1332387124-slideshow/', 'Click image to see more photos', 'http://l.yimg.com/os/152/2012/03/22/d761a49f3fcc99080a0f6a70670053cd-jpg_150905.jpg', '500', ' ', 'AP Photo/John Minchillo', ], [ [['Mohamed Merah', 10], ['prosecutor Francois Molins', 5]], 'http://news.yahoo.com/photos/four-dead-in-french-jewish-school-shooting-1332173151-slideshow', 'Click image to see more photos', 'http://l.yimg.com/cv/ip/ap/default/120321/2012_03_21t151508z_425380421_gm1e83l1sqs01_rtrmadp_3_france_shootings_raid.jpg', '630', ' ', 'REUTERS/Jean-Paul Pelissier', ], [ [['Shortly after he wrapped up his victory remarks', 2]], 'http://news.yahoo.com/photos/4-straight-romney-wins-washington-gop-caucus-1330835515-slideshow/', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/3/e9/3e9b0082c3c3111dcc19e3527ae94cc7.jpeg', '500', ' ', 'AP Photo/Steven Senne', ], [ [['best understands the problems of average Americans', 2]], 'http://news.yahoo.com/photos/4-straight-romney-wins-washington-gop-caucus-1330835515-slideshow/', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/3/e9/3e9b0082c3c3111dcc19e3527ae94cc7.jpeg', '500', ' ', 'AP Photo/Steven Senne', ], [ [['Group for Historic Aircraft Recovery', 7]], 'http://yhoo.it/GB2RVy', 'Click image to see more photos', 'http://l.yimg.com/os/152/2012/03/20/photo-1332257995646-4-0-jpg_171722.jpg', '630', ' ', 'AFP', ], [ [['xxxxxxxxxxxx', 11]], 'http://news.yahoo.com/photos/russian-grannies-win-bid-to-sing-at-eurovision-1331223625-slideshow/', 'Click image to see more photos', 'http://l.yimg.com/a/p/us/news/editorial/1/56/156d92f2760dcd3e75bcd649a8b85fcf.jpeg', '500', ' ', 'AP', ] ]
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Source: http://news.yahoo.com/us-sets-carbon-standard-power-plants-155842784.html
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While Ingram Micro VP of channel marketing Kirk Robinson wouldn?t tell Gennifer Biggs, managed services editor, Business Solutions magazine all the juicy details about the next step of the Business Intelligence offering that Ingram Micro will be rolling out at its VTN event this week, he did give Biggs some information. Watch the below short video for the details.
Video Rating: 5 / 5
Source: http://small-business-phones.info/?p=9654
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Every relationship needs counseling therapy once in a while so that there will be a time for the couple to express their feelings to one another, good or bad. Professional help from therapists can assist the couple in surviving the trials and circumstances they are in at the moment. The thing you need to know about counseling therapy is that it is not only for those having struggles with their relationship but it can be really helpful for those who are happy with their relationship status today. Those relationships which are in great condition can see this as an act to prevent unfortunate things to happen. This is something which both persons in the relationship benefit from since they are both working together.
Getting booked for an online counseling will be new for some, they call it online therapy and people just have to get used to it and avail the very accessible counselor. There are so many stuff you can get from the internet, just click what you need on any search engine you?re using and viola?the counselor you need could just be that one click away from where you are.
Act of Disloyalty
Relationships can be tested whenever one or both parties would go for infidelity. There will always be times where the trust can be broken and after that, communication will already be hard to establish from both parties thus you need now the help of a counseling to get back to where you were before.
Call of Duty
Relationships can be tested as well in terms of the couple?s careers, no matter where he is in his career now. Career issues are something which can be addressed healthily when experts in communication are there to help the couples.
Mid Life Blues
Relationships also are affected with issues concerning growing old since persons grow old and encounter changes in his or her self. This can be a threat to the relationship when one or both parties are undergoing stress with their old age. When couples go for counseling therapy, they will be more aware of the normal changes in growing old and how they can effectively cope up with the situation through therapeutic communication.
Problems Concerning Health
The relationship can definitely be affected when one person would experience an illness and threat to health. You have to know that not all couples have the same reactions to this situation; however, one thing is for sure. It can affect the relationship along with the stress brought by the illness. Couples are able to cope up healthily when there will be counseling therapy where communication is enhanced and promoted.
It will always be a rocky road at times. This is expected since two personalities have decided to be one and there will be clashing of their individualities. Effective communication is always the key and this can be achieved the moment couples decide to go for counseling and spare some time to express their feelings and emotions. The counseling therapy aims to always promote healthy relationships and coping mechanisms to the couples.
Type in Ben Wolf into Bing Search; do you find what you need?
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TODAY
By Rosemary Brennan and Marcus Mulick, E! Online
Just days after being released from treatment following a heart attack and a medically induced coma, comedian Gallagher suffered a second heart attack Sunday.
His rep confirms to E! News that the 65-year-old funnyman is now awake and resting in an Arizona hospital.
READ: Gallagher released from hospital after heart attack
The sledgehammer-wielding comedian was not feeling well Sunday and was taken by his son to the hospital. While there, he suffered a second heart attack.
"He had another minor heart attack today, but is resting well in a Sedona hospital," his spokeswoman tells E! News. "He was trying to gets a refill today, but nevertheless he is with family doing OK."
His family and friends are hoping he takes it easy and gets some rest, but apparently, the comic doesn't like the sound of that.
"Gallagher doesn't like people telling him what to do, but he just needs to rest," his rep continues. "We're just praying he'll listen."
PHOTOS: The Big Picture: Today's hot pics!
The inventor of the Sledge-o-Matic has hinted that he'll soon give up touring, recently saying, "I'm sick and tired of it." However, he doesn't plan on retiring from show business completely. This change would provide the comedian some much needed R&R and allow him to focus on his other passions: screenwriting, creating graphic novels and other projects that don't require such taxing travel schedules.
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{Diet to lose excess weight and build muscle means reducing your calories and do not let anyone explain otherwise. No weight loss gimmick or magic pill is going to go for it in your case until you such as a diet, or maybe a consistent exercise session.But, the process that comes with this approach has to do with unwanted fat and retaining the muscle on the other hand because if how many calories you take in is too low, even if losing yourself.|If you are with a fat reduction plan seeking some to develop some muscles too, you absolutely need the most suitable foods to generally be included in your diet. Here are foods that will help you lose fat, build mass quickly, and gaze after your entire body weight when already achieved.The 1st food throughout my list is much more. This may are quite important if you?re want to lose weight. These whole grain foods are awesome types of fiber. Fiber could enhance the metabolism, leading you to fuller longer, and may help detoxify and remove toxic substances outside of the body. Good much more are different from refined grains, that are unhealthy. So only tend to add following much more: brown rice, whole-wheat cereals and breads, barley, couscous, and oats.|There is a big misconception among people who making the effort to lose fat. People usually focus in on aerobic exercise if they?re want to lose weight. Furthermore, with females, especially, they avoid strength training. They fear which they will gain weight or get ripped through strength training. This may not be true. Weight training is actually a ideal for of exercise that may help you lose fat.|A number of people have got to joining the health club in droves. The goals for each individual may be different in the case of exercise. Some may be planning to build muscles in the interests of appearance, others should lose fat nevertheless others may be their for overall health and fitness enhancement reasons. But in spite of the reason or the explanation why you might be when you exercise or started to exercise with regularity, you will need to be sure you will get enough rest in an effort to properly recuperate from your very own exercise.|Losing a few pounds and staying fit is actually a goal for the majority of. Technologies will almost allways be coming along to assist us with the goals. With the amount fitness gadgets that you can purchase, the big question becomes that are good (as they quite simply have the ability to assist you build muscle and lose fat), that are bad, and that are ordinary crazy. Let?s examine several fitness gadgets these from each category.|It is possible to lose fat and build muscles within 60 days. Especially those with a decision to do this first must discover the course that will be to them. It might take trying few different program models of.Programs might add a DVD program, a fitness class, fitness professional as well as other program. There are plenty of programs around, which include DVD series, that are committed to weight loss and muscle creating within 60 days.|By far the most described subject from the gymnasium is truly the way of getting hard abs. Acquiring ripped abs displays to know how to lift heavy weights and eat good food, suddenly you become some type of specialist intended for exercise and fitness. Acquiring hard abs looks like it?s an out of the question target for many, yet this couldn?t wind up being farther from the particular truth, provided individuals check out the appropriate measures you could achieve abs.|A well known fact is muscle weighs well over fat. So whilst you?re dieting and exercising you might be becoming leaner, but you would possibly not see weight loss within the scale. It?s just a paradox for a few as they quite simply use a number planned make would like to weigh.Muscle burns fat more effectively; so bodybuilding whilst you?re losing fat is just what you must do. You?ll observe the definition of pound had been not used. We have distracted by the level of we weigh. It is more useful pinpoint how muscular and thin or big you intend to be?|A number of people workday after day, eating healthy foods, exercising as well as becoming the correct amount of sleep to generate energy level only to find make just cannot reach that end goal of having abs. For some people they are unable to remove that extra flab around their stomachs for others they seem slim enough nonetheless they cannot develop those extra muscles. If this describes in which case you maybe you are missing a crucial part of this healthy routine and this is diet supplements.|An interest that?s been just about the most hard address for weight-lifting or dieting advocates has become a 2010 diet to lose excess weight and build muscle with the same time. There?s always been debate suggesting that the two could never interact with each other, but that may not necessarily so anymore.From my experience, There really is that consistency together with calorie intake with continuous protein supply will hold muscle growth while slowly cutting stored fat.|For a fat reduction plan to succeed, the product really should be a ?transformed? physique; drastic decreases in unwanted fat accompanied by visually lean, toned muscles. Unfortunately, most loose weight programs fail; the dieter either surrenders, eating my way through site and gaining lots of the weight back or they starve themselves, shedding mass and essentially dealing accompanied by a scaled down version of their total old body. Ironically, the aforementioned case also results in future excess weight, to be the metabolism slows for a crawl and the entire body goes into ?starvation mode?. Under these conditions unwanted fat is spared with the valuation on metabolically expensive muscular tissues.|So, you intend to have perfect beach body. Now you?re able to. Follow these 3 realistic easy steps and you will be on your way to having that perfect body essential envy regarding. Imagine you might be at the lake walking passed beach babes, their pulses begin to race, their hearts skip a beat, you hear gasping, all because you eventually walked passed. I bet it feels good!|People spend hours on trainers different description. Would they assist you lose fat or build muscle? Or maybe there a better way?I own and employ a great deal of gym equipment. I truly do nothing like attending a gym to apply machines sweated on by lots of individuals.Nonetheless learned that using my Pilates or Elliptical walker (whilst I exploit the arms in conjunction with leg movements) never leave me feeling like I have done an awesome workout nor will they have a do much for my muscle creating therefore weight loss.|Wood you?ll be able to exercise at home and build your entire body that you may have always imagined of? The simple truth is. Employing a home training system allows you to produce a world-class physique without expensive gym memberships or home fitness equipment.In such a short article, we?ll cover most of the items that it is best to seek in the case of evaluating a building workout regime. Hopefully lots of people you?re finished going through this, you?ll know everything you should begin their work in the comfort of the home.|Most of the people dealing with their weight issues complain that whilst they are dieting on a regular basis, they?re just cannot lose fat. What folks are not able to seem to comprehend is the road many food affects your entire body. You have to always seek to follow healthy nutrition diet charts, instead of taking an unacceptable food in small portions.Nutritional foods definitely contribute to spend time playing in loose weight programs. Incredibly important are the exercising routines which improve metabolic process and support in burning of body fat of your body. Whatever excess calories you have from food, is generally burnt following the exercising patterns. Without following the proper methods, it?s very hard lose fat and gain muscles. Throughout this particular article, we shall focus through the simple steps which can help you lead a happy and healthy life while keeping shape.|The food industry is just about the most profitable across the world economy and America is known to be among the many heaviest countries across the world. Weight loss many people have issues utilizing weight, most are asking their healthcare providers and nutritionists how they can lose any additional pounds. You will find no magic pill, each will agree that the fastest and most effective weight to lose excess weight would be to build muscle, exercise and eat well.|In this post . Permit me to present to you when you consider utilising weights along with your treadmill cardio exercise of burning the maximum amount of unwanted fat.You can see the treadmill on it?s own is proven to raise your metabolic process and burn up fat particularly when you employ treadmill interval training along with other weight treadmill Fat loss routines. But to have the extra edge you will need to build mass. Lean muscle mass is to weight loss because doing so raise your metabolism.|Getting active to lose excess weight and build some minor mass just isn?t as difficult several would think. If you are one particular individuals who think that option sufficient time each day for it to be to a health club, particularly when you finally complete your property hold chores, then to understand. We glance at three household activities you?re able to do that will not only assist you tone and build some muscle and lose several of that weight you have been too busy loss of, and may assist you strengthen your home at the same time. Read that right, these include three activities you can do (some could possibly contact them projects or chores) at your home that can make you feel better with regards to you without so guilty about looking better!|In this post ., Most definitely i?ll provide you with how to construct massive quantities of muscle, and completely incinerate any fat that?s currently on the body. You can see, fat will not be something that is tough eliminate, it is simply that the majority of people try weight loss and burning that weight inside the wrong way, and most people don?t get results. Allow me to guarantee improvement with my routines, and are looking more trim and lean within a single week ? without the need to go hungry.|The truth about most diets due to the fact all eventually ended. If you are tired with crash diets and currently considering how to construct muscle and lose fat that stays gone, {it?s important to|you need to|it is critical to|it is advisable to|you?ll want to|it?s vital to|it
Source: http://scriptspharmacyonline.com/super-foods-you-should-be-eating-to-lose-weight-and-build-muscle/
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PR Newswire/Les Echos/ PR/20/12 Jean-Fran?ois Leprince-Ringuet joins Eutelsat as Chief Commercial Officer Paris, 23 March 2012 - Eutelsat Communications (Euronext Paris: ETL) announces that Jean-Fran?ois Leprince-Ringuet is joining the Group as Chief Commercial Officer and member of the Executive Committee, succeeding Andrew Wallace who is leaving Eutelsat to pursue other professional interests. Jean-Fran?ois will join Eutelsat on April 16 to assume overall responsibility for Eutelsat's commercial activities. Jean-Fran?ois Leprince-Ringuet brings 30 years of experience in IT and telecoms to Eutelsat. He has held commercial strategy, sales and marketing positions in Europe and North America at IBM, Hewlett-Packard, Cap Gemini and Bull, and has also been President of the IDATE(1) Foundation. Jean-Fran?ois is a French national and a graduate of the Ecole des Mines. "Eutelsat's ambition is to consolidate its place in broadcast and broadband markets with the highest quality of service, and to leverage innovation that can expand the role of satellites in the digital economy. Jean-Fran?ois Leprince-Ringuet's background in international telecom markets and his experience in developing sales and partner relationships will add to our commercial strengths and I am very pleased to welcome his broad talents to our management team, " commented Michel de Rosen, Chief Executive Officer of Eutelsat. "I thank Andrew for his commitment to our Group and wish him continued success in his career." About Eutelsat Communications Eutelsat Communications (Euronext Paris: ETL, ISIN code: FR0010221234) is the holding company of Eutelsat S.A.. With capacity commercialised on 28 satellites that provide coverage over the entire European continent, as well as the Middle East, Africa, India and significant parts of Asia and the Americas, Eutelsat is one of the world's three leading satellite operators in terms of revenues. As of 31 December 2011, Eutelsat's satellites were broadcasting more than 4,150 television channels. More than 1,100 channels are broadcast via its HOT BIRD video neighbourhood at 13 degrees East alone which serves over 120 million cable and satellite homes in Europe, the Middle East and North Africa. The Group's satellites also serve a wide range of fixed and mobile telecommunications services, TV contribution markets, corporate networks, and broadband markets for Internet Service Providers and for transport, maritime and in-flight markets. Eutelsat's broadband subsidiary, Skylogic, markets and operates access to high speed internet services through teleports in France and Italy that serve enterprises, local communities, government agencies and aid organisations in Europe, Africa, Asia and the Americas. Headquartered in Paris, Eutelsat and its subsidiaries employ just over 700 commercial, technical and operational professionals from 30 countries. (1) The IDATE association tracks global telecom, Internet and media markets. www.eutelsat.com For further information Press For further information Press Vanessa O'Connor Tel. : + 33 1 53 98 37 91 voconnor@eutelsat.fr Fr?d?rique Gautier Tel. : + 33 1 53 98 37 91 fgautier@eutelsat.fr Investors and analysts Lisa Finas Tel. : +33 1 53 98 35 30 investors@eutelsat-communications.com L?onard Wapler Tel. : +33 1 53 98 31 07 investors@eutelsat-communications.com The content and accuracy of news releases published on this site and/or distributed by PR Newswire or its partners are the sole responsibility of the originating company or organisation. Whilst every effort is made to ensure the accuracy of our services, such releases are not actively monitored or reviewed by PR Newswire or its partners and under no circumstances shall PR Newswire or its partners be liable for any loss or damage resulting from the use of such information. All information should be checked prior to publication.
Source: http://odugutumad.posterous.com/fe-investegate-eutelsat-communications-announ
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Social media has almost completely taken over Western civilization. Children are on social networking sites as they sit in class, their moms are on forums at home, and their fathers are blogging underneath the desk at work. Everything that the modern person needs is online now, from simple basics such as communication and friendship, to relationships, love, and consumer products. The good thing about this mass of communication is that it could give you with a easy means of promoting your goods through online social media marketing and other kinds of social media brand building.
The key to good online social media marketing is to create a strong media strategy that will give you the framework around which to build social media pages and networks. The strategy may help you decide where to aim your marketing and what varieties of conditions to avoid so you can be free to use your social media without fear of striking the wrong note. This is often significantly necessary in the age of the ?spammer?, an internet marketing device were marketing messages are sent unwanted and unwelcome, indiscriminately. Latest social media websites are usually full of people sending spam messages in forums, at the bottom of blog posts, and in Facebook messages.
The error that these spammers do is using their online social media marketing strategy in the wrong way. Instead of making an attractive and relevant post, message or web page they are rather bringing unrelated content into their messages.
This clashes with the adjoining social network and makes an attempt to sell something very obvious. So as to avoid being classed as a spammer, you may need to develop an effective online social media marketing strategy which understands the rules of social networking and utilizes them to good effect while planning a campaign.
The other problem many websites promoting things have is that their online social media marketing program was designed for them to create a sensation yet offers no long-term plan. The posts inflicting the sensation are usually excessively hyperbolic, aggressive, or exaggerated messages which are looked upon with distain by the complicated online society. Interest in your brand must be planned and applied carefully to make sure not to stir up dislike for your products by either spamming former clients or provoking viewers in an obvious and unattractive way. The minefield of social networking could be walked but it has to be made with care. There are various ways in which you may efficiently market your brand through the social media sites.
By: Cheryl Wilison
Posted:
Source: http://staceydahl.me/2012/online-social-media-marketing-for-the-modern-business/
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WASHINGTON (AP) ? A measure of future U.S. economic activity rose in February for the fifth straight month, fresh evidence that the economy is gaining momentum.
The Conference Board says its index of leading economic indicators rose 0.7 percent in February, after a 0.2 percent increase in January.
The measure of leading indicators is designed to anticipate economic conditions three to six months out. Its steady rise has coincided with other positive data that suggest the recovery is picking up ? including the best job growth in two years.
Most of the data had been previously released in separate reports.
The report "suggests that progress on jobs, output, and incomes may continue through the summer months, if not beyond," said Ken Goldstein, an economist at the Conference Board, a business research group.
Eight of the ten indicators tracked by the board increased last month, while only two fell. The largest contributors to the growth of the index were: declining applications for unemployment benefits, the spread between short-term and long-term interest rates and rising stock prices.
Rising building permits, average weekly hours worked in manufacturing, a credit index and two measures of manufacturing orders also pushed up the index.
Weekly applications for unemployment benefits fell last week to a four-year low, the Labor Department said in a separate report Thursday.
The two indicators that held back the index were a drop in consumer expectations and a decline in new orders for factory goods in a survey of purchasing managers.
A separate index measuring current business conditions rose for the third straight month, the board said.
Source: http://news.yahoo.com/gauge-us-economy-rose-0-7-percent-february-142000006.html
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Mark your calendars, Canadian fans. The UFC announced today they will visit the home and native land of welterweight champion Georges St. Pierre three times in the remainder of 2012.
They will start in Calgary on July 21, where Jose Aldo will fight a yet-to-be-named fighter. After that, it's UFC 152 in Toronto Sept. 22, and UFC 154 in Montreal Nov. 17. St. Pierre, who was present at the press conference, announced the Montreal date.
GSP also gave an update on his health, saying he is progressing smoothly and is hoping to be back by November.
"When you get an injury like I have and you're off for a long period of time, the only thing you wish is to get back fast as possible," he said. "I don't know if it will be in the U.S. or Canada, but I wish and I pray that I have a chance to perform in 2012. No matter where it will be, I want to come back and fight in 2012."
St. Pierre is a native of Montreal, and has enjoyed great success when fighting in front of the rabid home crowd Canada can provide. His last two fights were won in Canada, and he exacted revenge on Matt Serra, one of the few men to beat him, in Montreal.
Though he isn't likely to rush his recovery from an ACL tear, he also has plenty of motivation to be ready to go on Nov. 17.
Source: http://sports.yahoo.com/blogs/mma-cagewriter/ufc-eh-ufc-head-canada-three-times-2012-205133859.html
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[ [ [['As the standoff dragged into a second day', 7]], '28687424', '0' ], [ [['French police stepped up the search', 17]], '28667224', '0' ], [ [['Seeking to elevate his candidacy back to a general', 8]], '28660934', '0' ], [ [['The tragic story of Trayvon Martin', 4]], '28647343', '0' ], [ [['Karzai will get a chance soon to express', 8]], '28630306', '0' ], [ [['powerful storms stretching', 8]], '28493546', '0' ], [ [['basic norm that death is private', 6]], '28413590', '0' ], [ [['songwriter also saw a surge in sales for her debut album', 6]], '28413590', '1', 'Watch music videos from Whitney Houston ', 'on Yahoo! Music', 'http://music.yahoo.com' ], [ [['keyword', 99999999999999999999999]], 'videoID', '1', 'overwrite-pre-description', 'overwrite-link-string', 'overwrite-link-url' ] ]
Source: http://news.yahoo.com/clinton-calls-u-n-councils-move-syria-positive-001848734.html
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Contact: Lynn Yarris
lcyarris@lbl.gov
510-486-5375
DOE/Lawrence Berkeley National Laboratory
Future prospects for superior new organic electronic devices are brighter now thanks to a new study by researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab). Working at the Lab's Molecular Foundry, a DOE nanoscience center, the team has provided the first experimental determination of the pathways by which electrical charge is transported from molecule-to-molecule in an organic thin film. Their results also show how such organic films can be chemically modified to improve conductance.
"We have shown that when the molecules in organic thin films are aligned in particular directions, there is much better conductance," says Miquel Salmeron, a leading authority on nanoscale surface imaging who directs Berkeley Lab's Materials Sciences Division and who led this study. "Chemists already know how to fabricate organic thin films in a way that can achieve such an alignment, which means they should be able to use the information provided by our methodology to determine the molecular alignment and its role on charge transport across and along the molecules. This will help improve the performances of future organic electronic devices."
Salmeron and Shaul Aloni, also of the Materials Sciences Division, are the corresponding authors of a paper in the journal Nano Letters that describes this work. The paper is titled "Electron Microscopy Reveals Structure and Morphology of One Molecule Thin Organic Films." Other co-authors were Virginia Altoe, Florent Martin and Allard Katan.
Organic electronics, also known as plastic or polymer electronics, are devices that utilize carbon-based molecules as conductors rather than metals or semiconductors. They are prized for their low costs, light weight and rubbery flexibility. Organic electronics are also expected to play a big role in molecular computing, but to date their use has been hampered by low electrical conductance in comparison to metals and semiconductors.
"Chemists and engineers have been using their intuition and trial-and-error testing to make progress in the field but at some point you hit a wall unless you understand what is going on at the molecular level, for example, how electrons or holes flow through or across molecules, how the charge transport depends on the structure of the organic layers and the orientation of the molecules, and how the charge transport responds to mechanical forces and chemical inputs," Salmeron says. "With our experimental results, we have shown that we can now provide answers for these questions."
In this study, Salmeron and his colleagues used electron diffraction patterns to map the crystal structures of molecular films made from monolayers of short versions of commonly used polymers containing long chains of thiophene units. They focused specifically on pentathiophene butyric acid (5TBA) and two of its derivatives (D5TBA and DH5TBA) that were induced to self-assemble on various electron-transparent substrates.
Pentathiophenes - molecules containing a ring of four carbon and one sulfur atoms - are members of a well-studied and promising family of organic semiconductors.
Obtaining structural crystallographic maps of monolayer organic films using electron beams posed a major challenge, as Aloni explains.
"These organic molecules are extremely sensitive to high energy electrons," he says. "When you shoot a beam of high energy electrons through the film it immediately affects the molecules. Within few seconds we no longer see the signature intermolecular alignment of the diffraction pattern. Despite this, when applied correctly, electron microscopy becomes essential tool that can provide unique information on organic samples."
Salmeron, Aloni and their colleagues overcame the challenge through the combination of a unique strategy they developed and a transmission electron microscope (TEM) at the Molecular Foundry's Imaging and Manipulation of Nanostructures Facility. Electron diffraction patterns were collected as a parallel electron beam was scanned over the film, then analyzed by computer to generate structural crystallographic maps.
"These maps contain uncompromised information of the size, symmetry and orientation of the unit cell, the orientation and structure of the domains, the degree of crystallinity, and any variations on the micrometer scale," says first author Altoe. "Such data are crucial to understanding the structure and electrical transport properties of the organic films, and allow us to track small changes driven by chemical modifications of the support films."
In their paper, the authors acknowledge that to gain structural information they had to sacrifice some resolution.
"The achievable resolution of the structural map is a compromise between sample radiation hardness, detector sensitivity and noise, and data acquisition rate," Salmeron says. "To keep the dose of high energy electrons at a level the monolayer film could support and still be able to collect valuable information about its structure, we had to spread the beam to a 90 nanometer diameter. However a fast and direct control of the beam position combined with the use of fast and ultrasensitive detectors should allow for the use of smaller beams with a higher electron flux, resulting in a better than 10 nanometer resolution."
While the combination of organic molecular films and substrates in this study conduct electrical current via electron holes (positively-charged energy spaces), Salmeron and his colleagues say their structural mapping can also be applied to materials whose conductance is electron-based.
"We expect our methodology to have widespread applications in materials research," Salmeron says.
###
Aloni and Altoe say this methodology is now available at the Imaging and Manipulation of Nanostructures Facility for users of the Molecular Foundry.
This research was supported by the DOE Office of Science.
Lawrence Berkeley National Laboratory addresses the world's most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab's scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy's Office of Science. For more, visit www.lbl.gov.
The Molecular Foundry is one of five DOE Nanoscale Science Research Centers (NSRCs), national user facilities for interdisciplinary research at the nanoscale, supported by the DOE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please visit http://science.energy.gov.
?
AAAS and EurekAlert! are not responsible for the accuracy of news releases posted to EurekAlert! by contributing institutions or for the use of any information through the EurekAlert! system.
Contact: Lynn Yarris
lcyarris@lbl.gov
510-486-5375
DOE/Lawrence Berkeley National Laboratory
Future prospects for superior new organic electronic devices are brighter now thanks to a new study by researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab). Working at the Lab's Molecular Foundry, a DOE nanoscience center, the team has provided the first experimental determination of the pathways by which electrical charge is transported from molecule-to-molecule in an organic thin film. Their results also show how such organic films can be chemically modified to improve conductance.
"We have shown that when the molecules in organic thin films are aligned in particular directions, there is much better conductance," says Miquel Salmeron, a leading authority on nanoscale surface imaging who directs Berkeley Lab's Materials Sciences Division and who led this study. "Chemists already know how to fabricate organic thin films in a way that can achieve such an alignment, which means they should be able to use the information provided by our methodology to determine the molecular alignment and its role on charge transport across and along the molecules. This will help improve the performances of future organic electronic devices."
Salmeron and Shaul Aloni, also of the Materials Sciences Division, are the corresponding authors of a paper in the journal Nano Letters that describes this work. The paper is titled "Electron Microscopy Reveals Structure and Morphology of One Molecule Thin Organic Films." Other co-authors were Virginia Altoe, Florent Martin and Allard Katan.
Organic electronics, also known as plastic or polymer electronics, are devices that utilize carbon-based molecules as conductors rather than metals or semiconductors. They are prized for their low costs, light weight and rubbery flexibility. Organic electronics are also expected to play a big role in molecular computing, but to date their use has been hampered by low electrical conductance in comparison to metals and semiconductors.
"Chemists and engineers have been using their intuition and trial-and-error testing to make progress in the field but at some point you hit a wall unless you understand what is going on at the molecular level, for example, how electrons or holes flow through or across molecules, how the charge transport depends on the structure of the organic layers and the orientation of the molecules, and how the charge transport responds to mechanical forces and chemical inputs," Salmeron says. "With our experimental results, we have shown that we can now provide answers for these questions."
In this study, Salmeron and his colleagues used electron diffraction patterns to map the crystal structures of molecular films made from monolayers of short versions of commonly used polymers containing long chains of thiophene units. They focused specifically on pentathiophene butyric acid (5TBA) and two of its derivatives (D5TBA and DH5TBA) that were induced to self-assemble on various electron-transparent substrates.
Pentathiophenes - molecules containing a ring of four carbon and one sulfur atoms - are members of a well-studied and promising family of organic semiconductors.
Obtaining structural crystallographic maps of monolayer organic films using electron beams posed a major challenge, as Aloni explains.
"These organic molecules are extremely sensitive to high energy electrons," he says. "When you shoot a beam of high energy electrons through the film it immediately affects the molecules. Within few seconds we no longer see the signature intermolecular alignment of the diffraction pattern. Despite this, when applied correctly, electron microscopy becomes essential tool that can provide unique information on organic samples."
Salmeron, Aloni and their colleagues overcame the challenge through the combination of a unique strategy they developed and a transmission electron microscope (TEM) at the Molecular Foundry's Imaging and Manipulation of Nanostructures Facility. Electron diffraction patterns were collected as a parallel electron beam was scanned over the film, then analyzed by computer to generate structural crystallographic maps.
"These maps contain uncompromised information of the size, symmetry and orientation of the unit cell, the orientation and structure of the domains, the degree of crystallinity, and any variations on the micrometer scale," says first author Altoe. "Such data are crucial to understanding the structure and electrical transport properties of the organic films, and allow us to track small changes driven by chemical modifications of the support films."
In their paper, the authors acknowledge that to gain structural information they had to sacrifice some resolution.
"The achievable resolution of the structural map is a compromise between sample radiation hardness, detector sensitivity and noise, and data acquisition rate," Salmeron says. "To keep the dose of high energy electrons at a level the monolayer film could support and still be able to collect valuable information about its structure, we had to spread the beam to a 90 nanometer diameter. However a fast and direct control of the beam position combined with the use of fast and ultrasensitive detectors should allow for the use of smaller beams with a higher electron flux, resulting in a better than 10 nanometer resolution."
While the combination of organic molecular films and substrates in this study conduct electrical current via electron holes (positively-charged energy spaces), Salmeron and his colleagues say their structural mapping can also be applied to materials whose conductance is electron-based.
"We expect our methodology to have widespread applications in materials research," Salmeron says.
###
Aloni and Altoe say this methodology is now available at the Imaging and Manipulation of Nanostructures Facility for users of the Molecular Foundry.
This research was supported by the DOE Office of Science.
Lawrence Berkeley National Laboratory addresses the world's most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab's scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy's Office of Science. For more, visit www.lbl.gov.
The Molecular Foundry is one of five DOE Nanoscale Science Research Centers (NSRCs), national user facilities for interdisciplinary research at the nanoscale, supported by the DOE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please visit http://science.energy.gov.
?
AAAS and EurekAlert! are not responsible for the accuracy of news releases posted to EurekAlert! by contributing institutions or for the use of any information through the EurekAlert! system.
Source: http://www.eurekalert.org/pub_releases/2012-03/dbnl-boe032012.php
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